133? Woho!
Yep. Not only are there a lot of chapters, but the chapters themselves are usually pretty long.
I recommend this one if folks haven't read it yet. I started reading it a long time ago, and it was fun (or still is fun) because, much like Sienata, nosunlight updates quite frequently. She's still writing the "vignettes", which are really just more chapters of the main story. So this one isn't technically finished (even though, it seems she intended the story to end at chapter 103).
Can't Stand It is another relationship/family/figuring-out-how-to-live-together type AU.
There's an old thread about this story here in the forum that hasn't seen much action for a long time. I'll go bump it.
Another enormously long series is the "Sequence" series by fics_at_random. It's hard to exactly say how many chapters that one has because of the way it's been organized and updated. But, it's huge.